Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

作者：Howarth Ashlee J; Buru Cassandra T; Liu Yangyang; Ploskonka Ann M; Hartlieb Karel J; McEntee Monica; Mahle John J; Buchanan James H; Durke Erin M; Al Juaid Salih S; Stoddart J Fraser; DeCoste Jared B; Hupp Joseph T; Farha Omar K

来源：Chemistry - A European Journal, 2017, 23(1): 214-218.

DOI：10.1002/chem.201604972

• fullerene
• metal-organic frameworks
• pyrene
• singlet oxygen
• sulfur mustard

A fullerene-based photosensitizer is incorporated postsynthetically into a Zr-6 -based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min.

• 出版日期2017-1-1
• 单位西北大学