An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide-organic complex: synthesis, crystal structure and properties

作者：Yang, Mei-Si; Chen, Wei-Chao; Qin, Chao^*; Yao, Wei; Yin, Ying-Xue; Su, Zhong-Min^*

来源：New Journal of Chemistry, 2017, 41(19): 10532-10536.

DOI：10.1039/c7nj02011b

• PHOTOCATALYTIC PROPERTIES
• COORDINATION POLYMERS
• FRAMEWORK
• CLUSTERS
• CE
• POLYOXONIOBATES
• REACTIVITY
• CATALYSIS
• LINKERS
• LIGANDS

For the first time, an unprecedented 3D framework based on lanthanide-containing Nb/W mixed-addendum polyoxometalate [H3La8(H2O)(32)(C6H5NO2)(6)][SiW9Nb3O40](3)center dot 8H(2)O(1) has been obtained by utilizing the steam-assisted conversion method. Meanwhile, the stability, electrochemical behavior, and photoluminescence properties of 1 have also been discussed.

• 出版日期2017-10-7
• 单位东北师范大学