Non-interpenetrated Cu-based MOF constructed from a rediscovered tetrahedral ligand

作者：Patil Komal M; Telfer Shane G; Moratti Stephen C; Qazvini Omid T; Hanton Lyall R

来源：CrystEngComm, 2017, 19(48): 7236-7243.

DOI：10.1039/c7ce01818e

A stable non-interpenetrated MOF, <bold>UOF-1</bold> (UOF = University of Otago framework), was made by combining the rigid tetrahedral tetrakis(4-carboxyphenyl)adamantane (<bold>L</bold>) ligand and copper(ii) paddle-wheel SBU. This low-density open framework displayed excellent selectivity for CO2 over N2 at practical operating conditions.

• 出版日期2017-12-28
• 单位武汉科技大学