Homologous NiO//Ni2P nanoarrays grown on nickel foams: a well matched electrode pair with high stability in overall water splitting

作者：Zheng, Jinlong; Zhou, Wei^*; Liu, Tong; Liu, Shijie; Wang, Chengbo; Guo, Lin^*

来源：Nanoscale, 2017, 9(13): 4409-4418.

DOI：10.1039/c6nr07953a

• HYDROGEN EVOLUTION REACTION
• EFFICIENT BIFUNCTIONAL ELECTROCATALYSTS
• OXYGEN REDUCTION REACTION
• HIGH-PERFORMANCE
• METAL-OXIDE
• THIN-FILM
• DUAL-ELECTROCATALYST
• MOLYBDENUM CARBIDE
• NANOWIRE ARRAYS
• GRAPHENE OXIDE

Homologous NiO, Ni3S2, and Ni2P nanoarrays were obtained by thermolysis, sulfuration, and phosphorization of the Ni(SO4)(0.3)OH1.4 belt-like precursors. The three types of porous nickel compound films grown on nickel foam with a thickness of similar to 8 mu m have been used as anodes and cathodes in a two-electrode setup for overall water splitting. The electrode pairing of NixMy//NixMy (M = O, S, and P) for electrocatalysis in order of superiority is as follows: NiO//Ni2P > Ni3S2//Ni2P > Ni2P//Ni2P > Ni3S2//Ni3S2 > NiO//Ni3S2 > wNiO//NiO. The other two sets of NixMy with different thicknesses of similar to 5 and similar to 11 mu m also follow the abovementioned order. The well matched electrode pair of NiOOER//Ni2PHER only needs 1.65 V, whereas NiO//NiO pair needs 1.84 V to afford the current of 10 mA cm(-2) in 1 mol L-1 of aqueous KOH solution. In particular, the current density retention of the NiO//Ni2P reached 92% after 120 hours of electrolysis at 1.70 V (NiO//NiO only maintains 72% after 30-hour electrolysis). The novelty of this study focuses on fabricating a well matched electrode pair to substantially enhance its electrochemical performance and durability, which would provide a new insight into developing non- noble, highly efficient, and stable electrode pairs.

• 出版日期2017-4-7
• 单位北京航空航天大学