A novel route to realize controllable phases in an aluminum (Al3 )-doped VO2 system and the metal-insulator transition modulation

作者：Wu, Yanfei; Fan, Lele; Chen, Shuangming; Chen, Shi; Chen, Feihu; Zou, Chongwen^*; Wu, Ziyu

来源：Materials Letters, 2014, 127: 44-47.

DOI：10.1016/j.matlet.2014.04.094

• VO2
• Phase transformation
• Al-doping
• Phase structure
• Phase-transition temperature

The controllable M1 or M2 phases of Al3 -doped VO2 were successfully achieved through an effective and economical route, which combines a hydrothermal method and subsequent annealing treatment. The crystalline structure and the valence states of as-prepared samples were characterized by XRD, TEM, and XANES spectroscopy. Experiments showed that the Al3 dopants and the Ar flux rates in an annealing process played the important roles in the formation of stable M2 phase. Microstructural characterizations by SEM indicated that the size of Al-doped VO2 particles gradually reduced with increasing Al concentration. The phase transition property measured by DSC revealed that the metal-insulator transition temperature (TO could be tuned by the Al-doping concentration only in the formation of M2 phase.

• 出版日期2014-7-15
• 单位中国科学技术大学