Air- and moisture-stable secondary phosphine oxides as preligands in catalysis

作者：Ackermann Lutz^*

来源：Synthesis (Germany), 2006, 2006(10): 1557-1571.

DOI：10.1055/s-2006-926427

• asymmetric catalysis
• cross-coupling
• nucleophilic additions
• phosphorus
• transition metals

The application of secondary phosphine oxides to catalysis is reviewed. A survey of the literature up to summer 2005 is provided, covering the use of these air- and moisture-stable preligands in transformations catalyzed by transition-metal complexes and their use as precatalysts in nucleophilic catalysis.
1 Introduction
2 Syntheses of Phosphine Oxides and Their Metal Complexes Relevant to Catalysis
3 Transition-Metal-Catalyzed Reactions
3.1 Carbon-Substituted Secondary Phosphine Oxides
3.2 Heteroatom-Substituted Secondary Phosphine Oxides
3.3 Asymmetric Transition-Metal-Catalyzed Reactions
4 Nucleophilic Catalysis
5 Summary and Outlook.

• 出版日期2006-5-15