An NMR study of the structures of lanthanide diethylenetriaminepentaacetates

作者:Babushkina T A*; Klimova T P; Peregudov A S; Gol'tyapin Yu V; Lipengolts A A; Cherepanov A A; Kulakov V N
来源:Russian Journal of Coordination Chemistry, 2015, 41(1): 43-46.
DOI:10.1134/S1070328415010017

摘要

The paramagnetic chemical shifts in the H-1 and C-13 NMR spectra of lanthanide complexes (Ln = Eu, Yb, and Pr) with diethylenetriaminepentaacetic acid were analyzed. It was demonstrated that Eu+3 in aqueous solution can coordinate to one of the carboxylate groups in a chelating bidendate fashion through two O atoms.

  • 出版日期2015-1

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