A trio of nanoswitches in redox-potential controlled communication

作者:Pramanik Susnata; De Soumen; Schmittel Michael*
来源:Chemical Communications, 2014, 50(87): 13254-13257.
DOI:10.1039/c4cc05773b

摘要

A potential-controlled two-step bidirectional communication protocol between the nanoswitches [Cu(1)](+), 2 and 3 is set up, in which ligand followed by metal-ion oxidation drives two subsequent metal ion translocations (self-sorting) changing the switching state at each switch. The communication is reset to its starting point by a two-electron reduction.

  • 出版日期2014-11-11