A chiral metal-organic framework for sequential asymmetric catalysis

作者：Song Feijie; Wang Cheng; Lin Wenbin^*

来源：Chemical communications, 2011, 47(29): 8256-8258.

DOI：10.1039/c1cc12701b

A chiral metal-organic framework (MOF) of the lcy topology was constructed from the Mn-Salen derived dicarboxylic acid and the [Zn(4)(mu(4)-O)(O(2)CR)(6)] secondary building unit, and used in highly regio- and stereo-selective sequential alkene epoxidation/epoxide ring-opening reactions.

• 出版日期2011