Partial replacement of EPR by GTR in highly flowable PP/EPR blends: Effects on morphology and mechanical properties

作者：Lima Paulo Silva^*; Oliveira Jose Martinho; Ferreira Costa Vitor Antonio

来源：Journal of Applied Polymer Science, 2015, 132(22): 42011.

DOI：10.1002/app.42011

• blends
• compatibilization
• mechanical properties
• morphology
• recycling

This research analyzes the effect of ground tire rubber (GTR) and a novel metallocene-based ethylene-propylene copolymer (EPR), with high propylene content, on the morphology and mechanical behavior of ternary polymer blends based on a highly flowable polypropylene homopolymer (PP). The PP/EPR blends morphology, with very small domains of EPR dispersed in the PP matrix, indicates a good compatibility among these materials, which leads to a significant improvement on elongation at break and impact strength. The incorporation of EPR on the rubber phase of thermoplastic elastomeric blends (TPE) based on GTR and PP (TPEGTR) has a positive effect on their mechanical performance, attributed to the toughness enhancement of the PP matrix and to the establishment of shell-core morphology between the rubber phases. The mechanical properties of the ternary blends reveal that TPEGTR blends allow the upcycling of this GTR material by injection molding technologies.

• 出版日期2015-6-10