A simple synthesis of long nanostructured arrays of crystalline strontium titanates at low-temperatures

作者：Yin Liang; Gwak Yunki; Yu Choongho^*

来源：Journal of Materials Science, 2011, 46(21): 6835-6840.

DOI：10.1007/s10853-011-5643-0

Long aligned arrays of crystalline strontium titanate (SrTiO(3)) nanostructures were synthesized by using simple low-temperature processes that incorporate strontium into titanium oxides. Tubular nanostructures are often confine energy carriers that result in extraordinary transport behaviors in various semiconductors including strontium titanates, which are promising for developing efficient thermoelectric energy conversion materials. However, synthesizing a micron-to-milimeter scale array of one-dimensional ternary nanostructures has been difficult. Moreover, ternary compounds are often obtained as disordered cubic-shape particles at the end of complicated and/or long reactions. In this study, a two-step process-anodization for preparing amorphous titanium oxides and a subsequent thermal annealing process in a mixture of strontium hydroxide, ammonia, and water-was employed. Typical diameter and length of the tubes are similar to 150 nm and similar to 160 mu m, respectively. It has been found that the amorphous structure of titanium oxides plays an important role in obtaining high-purity long strontium titanate nanotubes at low temperatures (90 and 180 degrees C) with short reaction times. Comparative and systematic studies with different sample pre-treatments, etching times, temperatures, reaction times, and strontium concentrations revealed reaction mechanisms and key synthesis parameters, which may be utilized to obtain other ternary or quaternary nanostructured compounds such as barium or lead titanates.

• 出版日期2011-11