A giant M2L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

作者：Fazio Ettore; Haynes Cally J E; de la Torre Gema^*; Nitschke Jonathan R^*; Torres Tomas^*

来源：Chemical communications, 2018, 54(21): 2651-2654.

DOI：10.1039/c7cc09528g

An unprecedented Fe2Pc3 metallo-organic helicate has been assembled using a bidentate phthalocyanine (Pc) ligand, 2-formylpyridine and Fe(OTf)(2). This giant helicate has proved itself as a host for large redox-active guests such as fullerene and naphthalenediimide derivatives. Photoactivated electronic interactions between components occur in the host-guest complex.

• 出版日期2018-3-14