科研之友
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摘要
Iron is one of the most important elements in the biochemical processes in all living system, both deficiency or excess of iron will lead to metabolism disorder diseases. However, Fe3+ is one of the most efficient fluorescence quenchers among the transition-metal ions because of its paramagnetic nature. The realization of Fe3+ ratiometric and self-calibrated fluorescent sensor is highly-challenging. We synthesized a novel luminescent -OH functionalized EuOHBDC (Eu-2(OH-BDC)(3), OH-BDC=2-hydroxyterephthalic acid) by hydrothermal reaction and in situ ligand synthesis, and used it as a rare ratiomatric luminescent sensor for Fe3+ ions. The -OH functional group facilitates both electron transfer and binding interaction between EuOHBDC and Fe3+, which lead to luminescent quenching of ligand-based emission while enhancement of a new peak emission, and thus enables ratiometric detection of Fe3+. The relative fluorescent intensity ratio (I-375/I-427) increased linearly with increasing Fe3+ concentration in the 10-50 mu M range with 1.17 mu M (65 ppb) detection limit. The EuOHBDC also shows excellent selectivity towards different metal ions, particularly can discriminate Fe3+ and Fe2+ through different luminescent responses. This result clearly demonstrates the superiority of -OH functionalized MOF for Fe3+ detection, which can contribute to develop high performance luminescent probe for detection of metal ions in environmental and biomedical applications.
