A novel one-dimensional reduced Molybdenum(V) decorated with nickel coordination cations: Ni[Mo(6)O(12)(OH)(3)(PO(4))(HPO(4))(3)](2)[NI(H(2)O)(2)][Ni(H(2)O)(bipy) (2)](4)center dot 5H(2)O

作者：Guo Hong Xu^*; Wang Qing Hua; Chen Chen; Liang Min; Chen Ling

来源：Chinese Journal of Chemistry, 2008, 26(4): 640-644.

DOI：10.1002/cjoc.200890121

• hydrothermal synthesis
• crystal structure
• molybdenum phosphate
• one-dimensional chain-like
• catalytic activity

A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo(6)O(12)(OH)(3)(PO(4))(HPO(4))(3)](2)-[Ni(H(2)O)(2)][Ni(H(2)O)(bipy)2]4 center dot 5H(2)O (bipy=2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo(6)P(4)} clusters are linked via one Ni cation to form a Ni[Mo(6)P(4)](2) dimer unit, which is further connected together by additional nickel coordination complex ions to give 1-D molybdenum(V) phosphate chain-like structure. A probe reaction of the oxidation of benzaldehyde with H(2)O(2) using the title compound as catalyst was carried out in a liquid-solid system, showing that the compound had high oxidative catalytic activity to the reaction.

• 出版日期2008-4
• 单位闽南师范大学