The Formation of CuCl2-Specific Metallogels of Pyridyloxalamide Derivatives in Alcohols

作者:Dzolic Zoran*; Cametti Massimo; Milic Dalibor; Zinic Mladen
来源:Chemistry - A European Journal, 2013, 19(17): 5411-5416.
DOI:10.1002/chem.201204082

摘要

Isomeric pyridyloxalamide derivatives 13, which differed in the position of the nitrogen atom on the pyridyl ring, showed remarkably different gel-forming aptitudes in the presence of CuCl2 salt in alcohols. Whilst derivatives 1 and 3 formed a soluble complex and a solid precipitate, respectively, ligand 2 generated a remarkably metal- and anion-specific metallogel.

  • 出版日期2013-4