Diphosphino-functionalized MCM-41 anchored palladium(0) complex as an efficient catalyst for Heck arylation of conjugated alkenes with aryl halides

作者：Cai Mingzhong^*; Sha Junchao

来源：Catalysis Communications, 2007, 8(11): 1691-1696.

DOI：10.1016/j.catcom.2007.01.038

• supported palladium catalyst
• bidentate phosphine palladium(0) complex
• MCM-41
• heck arylation
• heterogeneous catalysis

Diphosphino-functionalized MCM-41 anchored palladium(0) complex (denoted as MCM-41-2P-Pd(0)) was conveniently synthesized from commercially available and cheap gamma-aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydrate. XRD and XPS spectroscopies were employed to characterize the title palladium complex. It was found that this complex is a highly active and stereoselective catalyst for Heck arylation of conjugated alkenes with aryl halides and can be reused many times without loss of activity.

• 出版日期2007-11
• 单位江西师范大学