Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine

作者：Bertke Jeffrey A; Bunge Scott D^*

来源：Dalton Transactions, 2007, (41): 4647-4649.

DOI：10.1039/b712054k

The reaction of 1,1,3,3-tetramethylguanidine (HTMG) with [UO(2)Cl(2)(THF)(2)] yielded [UO(2)Cl(2)(HTMG)(2)] 1, the first uranyl tetralkylguanidine adduct reported, further investigation led to the synthesis of [UO(2)(DBP)(2)(HTMG)(2)] 2 and [UO(2)(DBP-4-Me)(2)(HTMG)(2)] 3 via the reaction of [UO(2){N(SiMe(3))(2)}(2)(THF)(2)] with HTMG and the appropriate aryl alcohol, HO-2,6-(t)Bu(2)-4-RC(6)H(2) (R = H, DBP; R = CH(3), DBP-4-Me).

• 出版日期2007