摘要

We study the response of a spherical colloid under alternating electric fields (AC fields) by mesoscopic simulation method, accounting in full for hydrodynamic and electrostatic interactions. We focus on a special case of uncharged colloids. The main polarization mechanism is the %26quot;volume polarization%26quot;, where ionic currents are deflected by the core of the uncharged colloid. Specifically, we compute the polarizability of a single colloid and systematically investigate the effect of AC field frequency and salt concentration. The simulation results are compared with predictions from classical Maxwell-Wagner theory and electrokinetic theory.

  • 出版日期2013-4