A new binuclear potassium (I) complex with a novel 1D infinite water chain containing (H2O)(12) clusters

作者：Gao Enjun^*; Huang Yun; Zhu Mingchang; Wang Lei; Liu Fuchun; Liu Hongyan; Ma Shuang; Shi Qunzhi; Wang Ni; Shi Chunyue

来源：Inorganic Chemistry Communications, 2009, 12(9): 872-874.

DOI：10.1016/j.inoche.2009.07.003

• Potassium complex
• 2,2'-Azanediyldibenzoic acid
• Binuclear structure
• Dodecameric water cluster
• Fluorescence

A novel 1D infinite water chain made of(H2O)(12) Clusters containing two different chair water hexamers is found in the binuclear coordination compound, [K-2(L)(2)(phen)(4)]center dot 6H(2)O (1) (where L = 2,2'-azanediyldibenzoic dianion, phen = 1,10'-phenanthroline), which has been synthesized and structurally characterized by single-crystal X-ray diffraction. The fluorescence spectrum and thermogravimetric analysis (TGA) of the title complex I have been also discussed.

• 出版日期2009-9
• 单位沈阳化工大学