Mild oxidation of styrene and its derivatives with ionic manganese porphyrin immobilized in the similarly structured ionic liquid

作者:Liu Ye; Zhang Hong Jiao; Cai Yue Qin; Wu Hai Hong; Liu Xiu Li; Lu Yong*
来源:Chemistry Letters, 2007, 36(7): 848-849.
DOI:10.1246/cl.2007.848

摘要

Without the auxiliary involvement of axial ligands and organic solvents, the ionic manganese porphyrin 1c immobilized in [BPy][BF4] efficiently catalyzed the oxidation of styrene and its derivatives under mild conditions, affording high activity/oxide selectivity and good stability even after 5 recycling uses.