摘要
A hexanuclear complex of d(10)-d(10) transition metal with organosulfur ligand, Ag-6(py2t)(6) (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag-Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex.
- 出版日期2017-1-28
- 单位中国石油大学(华东); 中国地质大学(北京)