Bi-functional anodic TiO2 oxide: Nanotubes for wettability control and barrier oxide for uniform coloring

作者：Kim Sunkyu; Jung Minkyeong; Kim Moonsu; Choi Jinsub^*

来源：Applied Surface Science, 2017, 407: 353-360.

DOI：10.1016/j.apsusc.2017.02.166

• Anodization
• Color
• Wettability
• Nanotubes
• Barrier oxide

A uniformly colored TiO2, on which the surface is functionalized with nanotubes to control wettability, was prepared by a two-step anodization; the first anodization was carried out to prepare nanotubes for a super-hydrophilic or-hydrophobic surface and the second anodization was performed to fabricate a thin film barrier oxide to ensure uniform coloring. The effect of the nanotubes on barrier oxide coloring was examined by spectrophotometry and UV-vis-IR spectroscopy. We found four different regimes governing the color changes in terms of anodization voltage, indicating that the color of the duplex TiO2 was primarily determined by the thickness of the barrier oxide layer formed during the second anodization step. The surface wettability, as confirmed by the water contact angle, revealed that the single barrier TiO2 yielded 74.6 degrees +/- 2.1, whereas the nanotubes on the barrier oxide imparted super-hydrophilic properties as a result of increasing surface roughness as well as imparting a higher hydrophobicity after organic acid treatment.

• 出版日期2017-6-15