A facile approach for the synthesis of Z-scheme photocatalyst ZIF-8/g-C3N4 with highly enhanced photocatalytic activity under simulated sunlight

作者：Liu, Xiang^*; Zhang, Jing; Dong, Yuming; Li, Hexing^*; Xia, Yongmei; Wang, Haijun

来源：New Journal of Chemistry, 2018, 42(14): 12180-12187.

DOI：10.1039/c8nj01782d

• METAL-ORGANIC FRAMEWORKS
• CARBON NITRIDE
• HETEROJUNCTION
• COMPOSITES
• FABRICATION
• SEPARATION
• TIO2
• SIZE
• C3N4

In this study, ZIF-8-modified g-C3N4 (ZIF-8/g-C3N4) composites were successfully synthesized by hydrothermal reaction. The properties of the ZIF-8/g-C3N4 composites were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and photoluminescence (PL) spectroscopy. The results indicated that the ZIF-8 grew on the surface of the g-C3N4, forming closely contacted interfaces between the ZIF-8 and the g-C3N4 component. The photocatalytic performance of the ZIF-8/g-C3N4 composites was evaluated through the photodegradation of Rhodamine B (RhB). The results showed that 99.8% of RhB was degraded by the ZIF-8/g-C3N4 composite with 3 wt% of ZIF-8 in 60 min under simulated sunlight, which was much higher than that of pure g-C3N4 and ZIF-8. This highly enhanced photocatalytic activity of the ZIF-8/g-C3N4 composites can be mainly attributed to strong interfacial interaction promoting the photo-generated electron-hole separation and migration. The results of radical scavenger experiments showed that O-2(-) and h(+) were the dominant reactive species in the photocatalytic reaction. In addition, the ZIF-8/g-C3N4 composites showed excellent stability over several reaction cycles. Finally, a possible Z-scheme photocatalytic mechanism was proposed based on the experimental results.

• 出版日期2018-7-21
• 单位上海师范大学; 江南大学