科研之友
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摘要
A new hydrophobic ester functionalized task specific ionic liquid has been synthesized and its application explored in the synthesis of conjugated 1,3-diynes through Glaser coupling of terminal alkynes. Terminal alkynes undergo oxidative coupling smoothly in the presence of Cut-TEA catalytic system in hydrophobic ionic liquid under aerobic conditions to produce 1,3-diynes in excellent yields under mild conditions. The recovery and reusability of the catalyst is supported by the hydrophobic nature of the TSIL.
- 出版日期2017-9
