A chitosan-multiwall carbon nanotube modified electrode for simultaneous detection of dopamine and ascorbic acid

作者：Jiang LY; Liu CY; Jiang LP; Peng Z; Lu GH^*

来源：Analytical Sciences, 2004, 20(7): 1055-1059.

DOI：10.2116/analsci.20.1055

A chemically modified electrode based on a chitosan-multiwall carbon nanotube (MWNT) coated glassy carbon electrode (GCE) is described, which exhibits an attractive ability to determine dopamine (DA) and ascorbic acid (AA) simultaneously. The modified electrode exhibited a high differential pulse voltammetry (DPV) current response to DA at 0.144 V and AA at -0.029 V (vs. SCE) in a 0.1 mol l(-1) phosphate buffer solution (pH = 7.2). The properties and behaviors of the chitosan-multiwall carbon nanotube modified electrode (MC/GCE) were characterized using cyclic voltammetry (CV) and DPV methods. The mechanism for the discrimination of dopamine from ascorbic acid at MC/GCE is discussed. The linear calibration range for DA and AA were 5 x 10(-7) Mol l(-1) to 1 x 10(-4) mol l(-1) (r = 0.997), and 5 x 10(-6) Mol l(-1) to 1 X 10(-3) Mol l(-1) (r = 0.996), respectively. The MC/GCE showed good sensitivity, selectivity and stability.

• 出版日期2004-7
• 单位华中师范大学