A novel complex of mercury with double eta(6)-pi-aryl interactions

作者：Lang Ernesto Schulz^*; Tirloni Barbara; Vazquez Lopez Ezequiel M

来源：Inorganica Chimica Acta, 2009, 362(9): 3385-3387.

DOI：10.1016/j.ica.2009.03.016

• Mercury
• Tellurium
• Polymeric Hg-Te compounds

(MesTe)(2) reacts with HgBr2 to give [(HgBr(2)TeMes(2))2HgBr(2)], a polymeric one-dimensional assembly of (mu-Br)Hg and alternating mercury center dot center dot center dot eta(6)-pi-aryl interactions. This polymeric structure is based on [{HgBr2(TeMes(2))}(2)HgBr2] centrosymmetric units with three mercury atoms having two different coordination geometries. The central Hg-II ion is coordinated to four bromine atoms in the same plane and to two mesityl groups from TeMes(2) via eta(6)-pi-aryl interactions. Each TeMes(2) is bonded to one of the surrounding HgII ions through the tellurium atom. The central Hg-II ion is located in a crystallographic centre of inversion and sandwiched by its coordinating mesityl groups. The [{HgBr2(TeMes(2))}(2)HgBr2] units are linked by weak Hg center dot center dot center dot Br interactions in chains running along the c-axis.

• 出版日期2009-7-1