A Novel 3D Coordination Polymer Bearing Rare NbO-x-d Subnets: Synthesis, Structure, and Properties

作者：Wang, Tao; Zhang, Chenxi; Deng, Shengjun^*; Liu, Yijian; Xiao, Weiming; Zhang, Ning^*

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2018, 28(1): 308-313.

DOI：10.1007/s10904-017-0717-3

• Coordination polymer
• Subnet
• 4-Connected
• Photoluminescence
• Structural transformation

Employing the multicarboxylate and N-donor mixed ligands to react with Zn(NO3)(2)center dot 6H(2)O affords a new 3D compound [Zn-3(HBPTC)(2)(bmp)(2)(H2O)(2)]center dot 2H(2)O (1) (H4BPTC = biphenyl-3,3',4,4'-tetracarboxylic acid, bmp = 3,6-bis(imidazol-1-yl)pyridazine). Structural analyses show that compound 1 possesses a (4,4)-connected neutral framework bearing rare NbO-x-d subnets, and it represents the first replica of the theoretically predicted NbO-x-d/Im-3m -> Imm2 topology net. Moreover, compound 1 can demonstrate the interesting reversible structural transformation property induced by water molecules. Additionally, thermal stability and luminescence properties of 1 were investigated.

• 出版日期2018-1
• 单位中国科学院长春应用化学研究所; 南昌大学