A Cysteine-Based Tripodal Chelator with a High Affinity and Selectivity for Copper(I)

作者：Pujol Anais M; Gateau Christelle; Lebrun Colette; Delangle Pascale^*

来源：Journal of the American Chemical Society, 2009, 131(20): 6928-+.

DOI：10.1021/ja901700a

A C(3)-symmetric ligand containing three converging cysteine chains anchored on a nitrilotriacetic acid moiety has been synthesized. This tripodal pseudopeptide, which provides three soft sulfur donor groups, exhibits a very high affinity for Cu(I) in either a monometallic complex or the cluster species Cu(6)L(3).

• 出版日期2009-5-27
• 单位中国地震局