Diaquabis[2'-(4,5-diazafluoren-9-yl-idene)picolinohydrazidato-kappa N-2,O]zinc(II) tetrahydrate: a metal-water chain complex containing cyclic water hexamers

作者：Li Zhi Feng^*; Wang Chun Xiang; Du Chen Xia

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2006, 62: M488-M490.

DOI：10.1107/S0108270106035359

In the title compound, [Zn(C17H10N5O)(2)(H2O)(2)].4H(2)O, cyclic water hexa-mers forming one-dimensional metal-water chains are observed. The water clusters are trapped by the co-operative association of coordination interactions and hydrogen bonds. The Zn-II ion resides on a centre of symmetry and is in an octahedral coordination environment comprising two O atoms and two N atoms from two 2'-(4,5-diaza-fluoren-9-yl-idene)picolinohydrazidate ligands and two water molecules.

• 出版日期2006-10
• 单位郑州大学