Regioselective near-equatorial chlorination of C-s-C-70(CF3)(8)

作者:Goryunkov Alexey A; Samokhvalova Nadezhda A; Khavrel Pavel A; Belov Nikita M; Markov Vitaliy Yu; Sidorov Lev N; Troyanov Sergey I*
来源:New Journal of Chemistry, 2011, 35(1): 32-35.
DOI:10.1039/c0nj00591f

摘要

The chlorination of C-s-C-70(CF3)(8) by ICl occurs at near-equatorial [5,6] bond in agreement with quantum chemical predictions; structure of the synthesized C-s-C-70(CF3)(8)Cl-2 was proven by F-19 NMR spectroscopy and single crystal X-ray crystallography.

  • 出版日期2011