A membrane-, mediator-, cofactor-less glucose/oxygen biofuel cell

作者:Coman Vasile; Vaz Dominguez Cristina; Ludwig Roland*; Herreither Wolfgang; Haltrich Dietmar; De Lacey Antonio L; Ruzgas Tautgirdas; Gorton Lo; Shleev Sergey
来源:Physical Chemistry Chemical Physics, 2008, 10(40): 6093-6096.
DOI:10.1039/b808859d

摘要

We report the fabrication and characterisation of a non-compartmentalised, mediator and cofactor free glucose-oxygen biofuel cell based on adsorbed enzymes exhibiting direct bioelectrocatalysis, viz. cellobiose dehydrogenase from Dichomera saubinetii and laccase from Trametes hirsuta as the anodic and cathodic bioelements, respectively, with the following characteristics: an open-circuit voltage of 0.73 V; a maximum power density of 5 mu W cm(-2) at 0.5 V of the cell voltage and an estimated half-life of >38 h in air-saturated 0.1 M citrate-phosphate buffer, pH 4.5 containing 5 mM glucose.

  • 出版日期2008