A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

作者：Mowat John P S; Seymour Valerie R; Griffin John M; Thompson Stephen P; Slawin Alexandra M Z; Fairen Jimenez David; Dueren Tina; Ashbrook Sharon E; Wright Paul A^*

来源：Dalton Transactions, 2012, 41(14): 3937-3941.

DOI：10.1039/c1dt11729g

The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

• 出版日期2012