Diaquabis(4-chlorobenzoato-kappa O)(1,10-phenanthroline-kappa N-2,N ')cobalt(II)

作者：Ren, Yu-Lan; Liu, Yu-Jing; Song, Wen-Dong^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M1191-M1193.

DOI：10.1107/S1600536807013438

• single-crystal X-ray study
• T=293 K
• Mean sigma(C-C)=0.005 angstrom
• R factor=0.042
• wR factor=0.120
• data-to-parameter ratio=14.2

In the title complex, [Co(C7H4ClO2)(2)(C12H8N2)(H2O)(2)], the Co-II atom is six-coordinated in a distorted octahedral geometry by two O atoms from two 4-chlorobenzoate ligands, two N atoms from one 1,10-phenanthroline ligand and two water molecules. The molecules form O-H center dot center dot center dot O hydrogenbonded centrosymmetric dimers that are extended by additonal intra- and intermolecular hydrogen-bonding interactions to form infinite chains of dimers parallel to the a axis.

• 出版日期2007-5
• 单位牡丹江师范学院; 广东海洋大学