A brave new world: the heteroatom chemistry of 1,3,2,4-benzodithiadiazines and related compounds

作者：Blockhuys Frank^*; Gritsan Nina P; Makarov Alexander Yu; Tersago Karla; Zibarev Andrey V

来源：European Journal of Inorganic Chemistry, 2008, 2008(5): 655-672.

DOI：10.1002/ejic.200701051

• antiaromaticity
• fluorine heteroatom chemistry
• sulfur-nitrogen heterocycles
• molecular structures
• persistent radicals
• reactivity synthesis

This review highlights the most important advances in the heteroatom chemistry of 1,3,2,4-benzodithiadiazines (pi-excessive and formally antiaromatic heterocycles), covering methods for synthesis, nontrivial features of the molecular and pi-electronic structure, spectral properties, and reactivity, in particular the transformations into persistent pi-radicals. The chemistry of 1,3,2,4-benzodithiadiazines is compared to that of related chalcogen-nitrogen compounds, both cyclic and acyclic.

• 出版日期2008-2