科研之友
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摘要
The actual significance of the so-called compensation temperature T-c for micellization of surfactants is reviewed. It is demonstrated that it is possible to obtain as many T-c values as the number of temperature intervals in which the dependencies of enthalpy and entropy changes with temperature are analyzed. The value of each T-c will be the central value T-0 of each temperature interval. These two facts suggest that T-c is simply such experimental T-0. Thus any physical interpretation derived from T-c is unfounded.
- 出版日期2018-4
