Novel chiral recognition beyond the limitation due to the law of mass action: highly enantioselective chiral sensing based on non-linear response in phase transition events

作者：Hirose Keiji^*; Yachi Yuka; Tobe Yoshito

来源：Chemical Communications, 2011, 47(23): 6617-6619.

DOI：10.1039/c1cc11731a

Based on non-linear response in phase transition events exhibiting a sharp transmittance change, an intelligent chiral sensor capable of chirality amplification in aqueous media was designed and constructed as poly(N-isopropylacrylamide) having chiral pseudo-18-crown-6. Both sensitivity and selectivity of the sensor surmount the limitation due to the law of mass action.

• 出版日期2011