Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of a New 4d-4f Complex Based on 5-(isonicotinamido)-isophthalate

作者：Chen, Man Sheng^*; Deng, Yi Fang; Nie, Xue; Zhang, Chun Hua

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2012, 42(4): 513-517.

DOI：10.1080/15533174.2011.613684

• 5-(isonicotinamido)isophthalic acid
• crystal structure
• heterometallic
• luminescence

Hydrothermal reactions of Ag2O, 5-(isonicotinamido) isophthalic acid as well as Eu2O3 with a drop of CH3COOH results in formation of a new 4d-4f heterometallic coordination polymer [AgEu(INAIP)(2)(H2O)]center dot(H2O) (1) (INAIP = 5-(isonicotinamido)isophthalate). X-ray single-crystal structural analysis reveals that 1 is a three-dimensional framework. Furthermore, 1 also displayed photoluminescent properties in the red range at room temperature.

• 出版日期2012
• 单位衡阳师范学院