A novel 3-D heterobimetallic cyano-bridged coordination polymer incorporating Ag center dot center dot center dot Ag interaction: [Cu(dien)Ag(CN)(2)](2)[Ag-2(CN)(3)][Ag(CN)(2)]

作者：Zhou, HB; Dong, W; Liang, M; Liao, DZ^*; Jiang, ZH; Yan, SP; Cheng, P

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2004, 630(4): 498-500.

DOI：10.1002/zaac.200300418

• copper
• cyanide-bridging
• crystal structure

A three-dimensional cyano-bridged copper(II) complex, [Cu(dien)Ag(CN)(2)](2)[Ag-2(CN)(3)][Ag(CN)(2)] (1) (dien = diethylenetriamine), has been prepared and characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P2(1)/n with a = 6.988(2), b = 17.615(6), c = 12.564(4) Angstrom, beta = 90.790(5)degrees. The crystal consists of cis-[Cu(dien)](2+) units bridged by [Ag(CN)(2)](-) to form a zig-zag chain. The Ag atoms of the free and bridging [Ag(CN)(2)](-) link together to form additional infinite zig-zag chains with short Ag...Ag distances. The presence of Ag...Ag interactions effectively increases the dimensionality from a 1-D chain to a 3-D coordination polymer.

• 出版日期2004-4
• 单位南开大学; 现代配位化学国家重点实验室; 结构化学国家重点实验室; 北京大学; 中国科学院福建物质结构研究所; 南京大学