摘要

The curing reaction kinetics of epoxy system in epoxy asphalt concrete was studied by means of non-isothermal analysis kinetics method combined with linear heating-up data of differential scanning calorimetry (DSC) at several scan speed rates. Taking advantage of Netzsch Thermokinetics Diffusion Control software, a precise model of this reaction was obtained by Friedman differential and nonlinear regression methods. The reaction energy and order can be solved with Kissinger equation and crane equation. Using this model, the conversion rate can be calculated under given conditions. The results show that temperature rise can greatly shorten the required curing time. The results also show that the time of conversion rate reaching 80 percent is much shorter than that of complete curing. The curing rate is over ten times when the pavement temperature is at 60°C than at 30°C. Therefore, it is recommended that epoxy asphalt concrete pavement be constructed in high-temperature season. Usually, the pavement temperature exceeds 30°C in a whole day and the maximum temperature can reach up to 60°C during hot summer season. Under this condition, the conversion rate reaches 80 percent in two weeks with the Marshall Stability value nearly reaching 40 kN, which is a value advised to open the pavement to traffic.

  • 出版日期2011

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