Hydration of MgO(100) Surface Promoted at < 011 > Steps

作者:Sasahara Akira*; Murakami Tatsuya; Tomitori Masahiko
来源:Journal of Physical Chemistry C, 2015, 119(15): 8250-8257.
DOI:10.1021/acs.jpcc.5b01759

摘要

Dissolution of magnesium oxide (MgO)(100) surfaces in water was examined by an atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS) techniques. MgO(100) surfaces annealed at 1273 K in air for 288 h showed rectangular terraces surrounded by multiatomic height steps along the < 011 > directions. After immersion in water, bank-like structures appeared along the < 011 > steps: the end of the terraces remained smooth, while the inner regions of the terraces were roughened and subsided with respect to the end. Epitaxial growth of Mg(OH)(2) from the < 011 > steps toward the inner regions of the terraces is proposed.

  • 出版日期2015-4-16