Hydrolytic Decomposition of Tetramethylammonium Bis(trifluoromethyl)aurate(I), [NMe4][Au(CF3)(2)]: A Route for the Synthesis of Gold Nanoparticles in Aqueous Medium

作者:Zopes David; Kremer Silke; Seherer Harald; Belkoura Lhoussaine; Pantenburg Ingo; Tyrra Wieland; Mathur Sanjay*
来源:European Journal of Inorganic Chemistry, 2011, 2011(2): 273-280.
DOI:10.1002/ejic.201000863

摘要

Monodisperse gold nanoparticles (AuNPs) were obtained by hydrolytic decomposition of a new molecular precursor, tetra-methylammonium. bis(trifluoromethyl)aurate(I), [NMe4] [Au(CF3)(2)], which has been characterised by spectroscopic and single-crystal X-ray diffraction analyses. On account of the simple and high-yield synthesis, the title compound represents a versatile synthon and an alternative to the commonly used chloroauric acid (HAuCl4).

  • 出版日期2011-1