Activation of Peroxymonosulfate by CuNi@C Derived from Metal-Organic Frameworks Precursor

作者：Huang, Xue; Zhang, Jing^*; Zhang, Xiao; Wu, Qing-Ping; Yan, Chun-Hui

来源：Australian Journal of Chemistry, 2018, 71(11): 874-881.

DOI：10.1071/CH18260

• HETEROGENEOUS CATALYSTS
• EFFICIENT DEGRADATION
• OXIDATION
• SELECTIVITY
• HYDROGENATION
• NANOPARTICLES
• CU-3(BTC)(2)
• GENERATION

Calcined Cu-based metal-organic frameworks impregnated with nickel nitrate catalysts (CuNi@ C) were synthesised. X-Ray diffraction, scanning electronic microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy techniques were applied for the characterisation of the synthesised catalyst, which revealed an octahedral particle shape, rough surface, and metallic copper (Cu, CuO) and nickel (Ni, NiO) particles. CuNi@ C was fabricated as a novel peroxymonosulfate (PMS) activator for the oxidative degradation of Acid Orange 7 (AO7) in aqueous media. Results showed that the CuNi@C/PMS system can efficiently degrade nearly 100% of 0.02 mmol L-1 AO7 within 60 min. In addition, the trapping experiments confirmed the participation of sulfate radicals (SO4 center dot-) and hydroxyl radicals (HO center dot) as reactive species in the system. Furthermore, the effects of parameters including catalyst and PMS dosages, initial concentration of AO7, and pH were studied. Results showed that the decolourisation efficiency increased with the increase of catalyst dosage, but decreased with the increase of AO7 concentration. The optimal PMS concentration was 0.675 mmol L-1, and initial pH showed no significant effect on the degradation of AO7. Moreover, the CuNi@ C could be reused four times with good activity and reusability. Findings revealed that the CuNi@ C/PMS system shows potential for degrading contaminants in the environment, due to its catalytic activity and non-negligible adsorption.

• 出版日期2018
• 单位四川大学