A rapid and convenient oxidation of secondary alcohols

作者：Dip Irene; Gethers Christina; Rice Tonya; Straub Thomas S^*

来源：Tetrahedron Letters, 2017, 58(28): 2720-2722.

DOI：10.1016/j.tetlet.2017.05.085

• Alcohol
• Oxidation
• Selective
• Mechanism

A rapid (normally 20 min to 2 h) and selective oxidation of secondary alcohols to ketones can be achieved using 0.4 equivalents trichloroisocyanuric acid and 1.2 equivalents pyridine at room temperature in ethyl acetate. A likely mechanism for the reaction is proposed.

• 出版日期2017-7-12