Hydration structure of strongly bound water on the sulfonic acid group in a Nafion membrane studied by infrared spectroscopy and quantum chemical calculation

作者：Shimoaka T; Wakai C; Sakabe T; Yamazaki S; Hasegawa T^*

来源：Physical Chemistry Chemical Physics, 2015, 17(14): 8843-8849.

DOI：10.1039/c5cp00567a

The hydration structure of the 'strongly bound water' around the sulfonic acid (SA) groups in Nafion, which has recently been revealed by H-1 NMR spectroscopy (Anal. Chem., 2013, 85, 7581), is studied using infrared spectroscopy with the aid of quantum chemical (QC) calculations. During a heated drying process, bulky water is firstly dehydrated, which is followed by the disappearance of the hydronium ion and the appearance of bands that have been assigned to the fully dehydrated species at 140 degrees C. However, a spectral simulation based on QC reveals that the spectrum at 140 degrees C comes from the SA group associated with a single-water molecule via two H-bonds. This implies that a thoroughly dried membrane is unavailable even at 140 degrees C, and the involved water corresponds to the 'strongly bound water.' The QC-analytical results are experimentally confirmed by evolved gas analysis mass spectrometry (EGA-MS). At ca. 300 degrees C, which is the temperature where the SA group is selectively decomposed, the molecular fragment of SO2 is observed accompanying water molecules as expected. This confirms that the last single-water molecule can remain on the SA group until the thermal decomposition.

• 出版日期2015