New layered cobalt oxyfluoride, Sr2CoO3F

作者:Tsujimoto Yoshihiro*; Li Jun J; Yamaura Kazunari; Matsushita Yoshitaka; Katsuya Yoshio; Tanaka Masahiko; Shirako Yuichi; Akaogi Masaki; Takayama Muromachi Eiji
来源:Chemical communications, 2011, 47(11): 3263-3265.
DOI:10.1039/c0cc05482h

摘要

The first Ruddlesden-Popper type layered cobalt oxyfluoride, Sr2CoO3F, has been synthesized under a pressure of 6 GPa at 1700 degrees C and shown to adopt a K2NiF4-type structure with distorted square pyramidal coordination around Co and with O/F disorder at the apical sites.

  • 出版日期2011