A synthetic approach to a fullerene-rich dendron and its linear polymer via ring-opening metathesis polymerization

作者:Kim Jonggi; Yun Myoung Hee; Lee Junghoon; Kim Jin Young; Wudl Fred; Yang Changduk*
来源:Chemical communications, 2011, 47(11): 3078-3080.
DOI:10.1039/c0cc05470d

摘要

Through the esterification of an acyl chloride functionalized fullerene precursor with dendritic alcohol, a fullerene-rich dendron containing a norbornene unit at the focal point is prepared for ring-opening metathesis polymerization to obtain its linear polymer with a unimodal and narrow molar mass distribution (PDI = 1.08) by a progressive addition of catalysts.

  • 出版日期2011