Aliphatic Glucoside, Zanthoionic Acid and Megastigmane Glucosides: Zanthoionosides A-E from the Leaves of Zanthoxylum ailanthoides

作者:Teshima Serika; Kawakami Susumu; Sugimoto Sachiko; Matsunami Katsuyoshi; Otsuka Hideaki*; Shinzato Takakazu
来源:Chemical & Pharmaceutical Bulletin, 2017, 65(8): 754-761.
DOI:10.1248/cpb.c17-00211

摘要

From the leaves of Zanthoxylum ailanthoides, 4'-O-p-E-coumaric acid esters of 2-propanol beta-D-glucopyranoside, megastigmane and megastigmane glucosides were isolated. Their structures were elucidated by spectroscopic evidence. The absolute configurations of the megastigmane and aglycone of megastigmane glucosides were determined by the octant rule and modified Mosher's method after protection of carboxylic acids by p-bromophenacyl esters and primary alcohols by pivaloyl esters.

  • 出版日期2017-8