A stepwise loading method to magnetically responsive Pt-Fe3O4/MCNT catalysts for selective hydrogenation of 3-methylcrotonaldehyde

作者：Song Shaofei; Yu Jianyan; Xiao Qiang^*; Ye Xiangrong; Zhong Yijun; Zhu Weidong

来源：Nanoscale Research Letters, 2014, 9(1): 677.

DOI：10.1186/1556-276X-9-677

• Controlled particle sizes
• External magnetic field
• Inductively couplings
• Liquid-phase hydrogenation
• Magnetic
• Plasma-atomic emission spectroscopy
• Selective hydrogenation
• Unsaturated aldehydes

Pt-loaded multi-walled carbon nanotubes (Pt/MCNTs) and magnetically responsive Pt-Fe3O4/MCNT catalysts were prepared by a stepwise loading of preformed Pt and Fe3O4nanoparticles onto multi-walled carbon nanotubes (MCNTs). The structure, composition, and magnetism of the catalysts were characterized by X-ray diffraction (XRD), TEM, H2-O2titration, inductively coupling plasma-atomic emission spectroscopy (ICP-AES), and superconducting quantum interference device (SQUID) techniques. Ascribed to the well-controlled particle size in the preformed Pt colloids, Pt particles in the consequent Pt/MCNT and Pt-Fe3O4/MCNT catalysts are of high uniformity and dispersion. The prepared Pt catalysts show an excellent catalytic performance in the liquid phase hydrogenation of 3-methylcrotonaldehyde, one of typical α,β-unsaturated aldehydes. A very high selectivity to 3-methylcrotonalcohol of 98% at a conversion of about 80% was available on the magnetic Pt-Fe3O4/MCNT catalyst. The magnetic catalyst, with good superparamagnetism, can be easily recovered from the liquid phase system under the external magnetic field. Moreover, both the Pt/MCNT and magnetic Pt-Fe3O4/MCNT catalysts show a good recyclability, confirmed by five cycles of reusage.

• 出版日期2014
• 单位浙江师范大学