A novel -Pb-O-Pb-Cu-Cl- inorganic layer-based pillared-layer framework: Synthesis, crystal structure and fluorescent property

作者：Song, Jiang-Feng^*; Wen, Hui-Fang; Zhang, Wen; Yao, Rui-Chao; Zhou, Rui-Sha; Xu, Xiao-Yu^*

来源：Inorganic Chemistry Communications, 2018, 95: 100-103.

DOI：10.1016/j.inoche.2018.07.017

• Lead
• Pillared-layer
• Copper halide
• Inorganic layer

A novel pillared-layer coordination polymer containing -Pb-O-Pb-Cu-Cl- inorganic sheets, [PbCuCl(3.5-pydc)](n) (1) (3.5-H(2)pydc = pyridine-3,5-dicarboxylic acid), was obtained through the hydrothermal method. In compound 1, two symmetry-related Pb centers are bridged into a Pb2O2 dimer by two symmetrically carboxyl oxygen atoms from 3,5-pydc(2-) anions, each Pb2O2 dimer links four equivalent units into a 2D puckered Pb-O-Pb layer. Two symmetry-related Cu ions are bridged into a Cu2Cl2 dimer by two chlorine ions. Thus the -Pb-O-Pblayer and Cu2Cl2 dimers are joined into a novel 2D puckered -Pb-O-Pb-Cu-Cl- inorganic layer. The 2D -Pb-O-PbCu-Cl- inorganic layers are further pillared to form a 3D network through 3,5-pydc(2-) anions. To the best of our knowledge, the pillared-layer framework based on -Pb-O-Pb-Cu-Cl- inorganic layers has never been reported previously. Compound 1 exhibits weak blue light emission with the maximum at 383 nm upon excitation at 260 nm.

• 出版日期2018-9
• 单位中北大学