Alloy 800H under supercritical water conditions: a flow reactor study of corrosion and hydrogen evolution

作者:Choudhry K I*; Svishchev I M; Orlovskaya L
来源:Materials and Corrosion-werkstoffe Und Korrosion, 2015, 66(12): 1430-1434.
DOI:10.1002/maco.201508315

摘要

Hydrogen evolution and corrosion rates for an Alloy 800H flow-through reactor operating under supercritical water conditions were determined. Experiments were performed in the temperature range of 650 to 750 degrees C both with deoxygenated feed water, with an O-2 concentration of less than 10 mu g L-1 (ppb), and with a high oxygen concentration of around 20 mg L-1 (ppm). Effective rate constants for hydrogen evolution during the corrosion of an Alloy 800H were calculated to be 2.52 x 10(-11), 2.88 x 10(-11) and 4.30 x 10(-11) molcm (-2) s(-1), for the reactor temperatures of 650, 700 and 750 degrees C, respectively.

  • 出版日期2015-12